• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The active surface of the anode is formed by a row of parallel bars (4), spaced apart from each other in one plane, and electrically connected to a bar (3) supplying the electric current. The total surface area (Fa) of bars (4), and the area (Fp) occupied by the assembly of bars (4), conforms with the formula is greater than or equal to Fa:Fp is greater than or equal to 2. Bars(4) pref. have a rectangular cross-section, where the short side (B) is parallel with the flat wide surface of the anode, and the long side (T) is parallel with the thickness of the anode. The ratio B:T is pref. between 1:2 and 1:10; B is pref. 0.5-2.5 mm; and T is pref. 5-25 mm. The space (A) between two adjacent bars(4) is pref. A simple, inexpensive anode permitting the cathodic deposition of metals with high purity while saving electrical energy.
    公开号:SU1069633A3
    申请号:SU813244705
    申请日:1981-02-13
    公开日:1984-01-23
    发明作者:Коциоль Конрад；Венк Эрих
    申请人:Конрадти Гмбх Унд Ко Металлэлектроден,Кг (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to a coated anode for the electrolytic production of metals, the working surface of which is formed parallel to each other by rods electrically connected to a current-supply busbar, spaced apart from one another.
     A known anode for the electrolytic production of metals, made of titanium, placed in the same plane parallel to each other with coated rods connected to a current-carrying bus tlH.
    The disadvantages of this anode should be attributed to high consumption, electricity and high cost of construction.
    The closest to the invention according to the technical essence and the achieved result is an anode for electrolytic production of metals, made of titanium, placed in one plane parallel to one another with coated rods connected to the current-supply bus, with the rods made in the form of strips, rods, semi-cylinders or V-shaped elements; working rods are made of platinum and / or oxides of platinum and / or electrically conducting non-stoichiometric oxide and / or non-precious metal and / or its oxide and / or mixtures thereof, and at least one plate of rectangular cross section is welded across D21 rods.
    The disadvantages of the known anode should include a large power consumption.
    The purpose of the invention is to reduce power consumption.
    The goal is achieved by the fact that the anode for electrolytic production of metals, made of titanium, are arranged in one plane parallel to each other with coated rods connected to a current-carrying bus, while the rods are made in the form of strips, rods, half-cylinders or U-shaped elements forms, the working coating of the rods is made of platinum and / or oxides of platinum, and / or electrically conducting non-stoichiometric oxide, and / or non-precious metal, and / or its oxide, and / or their mixtures and at least one plate The rectangular section is welded across the upper layers, the ratio of the total surface of the rods A to the occupied: the entire core structure of the surface p is 6 f / vll 2, the ratio of the short and long sides of the rectangular cross section of the rods is 1: (2-10) / width of each rod to
    . the distance between the axis of symmetry of two adjacent rods is 1: (4-6), the rod width parallel to the arrangement plane is 0.5-0.25 mm, the depth of the rod measured 5 perpendicular to the anode plane is 5-25 mm and the distance between two adjacent rods is A 2 mm.
    Figure 1 shows the plane of the anode, top view; on
    Fig. 2 is a view of the structure parallel to the plane of arrangement; in FIG. 3, node 1 in FIG. 2; figure 4 - node fl in figure 1.
    5 On the support brackets 2 on the edge of the loading window of the electrolysis tank 1 there is a current supply bus 3, connected by a contact bus 4 to a current source. Tokopodvod shcha
    Q bus 3 carries a series of rods 5, representing the working surface of the anode. Rods have a rectangular cross-section of a width of a width of T. Depth. In this case, the rods
    5 are oriented TaKHiJt in the way that their depth T passes perpendicular to the plane of the location of the rods. The surface occupied by the rods is determined by the length of the rods Lj and the distance L $ between the outer sides of the two outer rods of the anode structure. The rods 5 are located with distance A in light of one relative to the other.
    5 The electrical and mechanical connection of current-carrying tires, made, for example, of copper, with rods 5, made of, for example, coated with titanium, is shown in FIG. 3. The busbar busbar 3 and the rods 5 are located in the same plane so that the upper and end surfaces of the rods 5. adjacent to the bottom surface of the connecting cable 3. The current connecting bus 3 is connected to the rods 5 by two connecting strips b located on both sides of the current leading busbar, parallel to the current leading bus and precisely made of titanium with a coating. The connecting strips 6 are fastened with screws 7ok and nuts 76 to the busbar 3. The rods 4 are connected to the connecting strips 6 by spot welding 8. To further tighten the anode structure, several transverse rods are connected by spot welding to the rods 5
    0 9, made in exactly the same way with coated titanium. In this case, successively located river rods 9 are alternately arranged on one or the other side of the plane of the location of the rods 5.
    Example. The rods 5 have a length J, 5J equal to 1170 mm, while their width B is 2 mm, and the depth T is 12 mm. The clear distance A between two adjacent rods 5 is 8 mm. The total LS length of the anode structure is 852 mm. 82 rods are provided.
    The anode is designed for a current of 600 A, respectively, for a density of -current on the anode side of 355 A / m (p). With a current of 600 A in the anode arises. with a 4th voltage drop of only about 100 mV.
    The design of the anode is very tough and durable. This is a result of not only the connection of the rods 5 with the busbar 3 by means of connecting strips 6 and spot welding of the rods with these connecting strips 6, but also by the additional arrangement of transverse rods 9 having a diameter of 4 mm. Thus, each plate rod 5 is fixed with seven welding points, ki.
    The anode is simple in design, relatively cheap to manufacture due to the small amount of material has a very large geometric surface. It weighs about 12 kg without current lead 3. The total surface of the rods l. To which the coating is applied is.
    including contacts, about 3 m. The working surface of the anode, i.e. The surface immersed in the electrolyte is approximately 2.4 m, which at 600 A gives a value (anodic 5 current density) of about 250 A / m% (}. The actual physical anodic current density resulting from the extremely large surface of the coating is This is only 5% of the value of 3. Based on this and the catholytic efficiency of the active components of the coating, a constant low oxygen pressure at the anode is obtained over a long period of time.
    5 operation.
    The coating on the surface of the anode protruding from the bath serves to protect the titanium parts of the anard from corrosion,
    0 The current load of the copper current-carrying bus 3 is relatively small (about 0.8 A / mm with a current of 600 A on the anode) making it possible to make new holes in the current-carrying bus 3 at a length of L 85 852 mm. Each hole 6a in the connecting strip 6 receives a current. around 33 A. Due to this small partial current in the contact zones and good contact coverage, the fall does not remain constant in these areas for a long service life.
    5- Phage.g
    FIG.
    权利要求:
    Claims (1)
    [1]
    ANODE FOR ELECTROLYTIC PRODUCTION OF METALS made of titanium rods arranged in the same plane parallel to one another with coatings connected to a current-carrying bus, while the rods are made in the form of strips, rods, half-cylinders or elements of a образ -shaped shape, the working coating of the rods is made of platinum and / or platinum oxides, and / or an electrically conductive non-stoichiometric oxide, and / or base metal, and / or its oxide, and / or mixtures thereof, and at least one rectangular weld plate across the rods, which is explained by the fact that, in order to reduce energy consumption, the ratio of the total surface of the rods to the surface Er occupied by the entire rod structure is 6 ·> ΓΑΡρ ·> 2, the ratio of the short and long sides of the rectangular cross-section of the rods 1: (2-10), the ratio of the width of each rod to the distance between the axes of symmetry of two adjacent rods 1: (4-6), the parallel arrangement of the width k being 0.5-2.5 mm, the plane of the rods commensurate perpendicular to the plane of the anode, the depth of the rod 5 -2.5 mm and distance m The distance between two adjacent rods is A i 2 mm.
    SU .... 1069633>
    X
    类似技术:
    公开号 | 公开日 | 专利标题
    US3676325A|1972-07-11|Anode assembly for electrolytic cells
    US3707454A|1972-12-26|Anode and base assembly for electrolytic cells
    EP0271924B1|1991-09-04|Permanent anode for high current density galvanizing processes
    US6254743B1|2001-07-03|Expanded titanium metal mesh
    CA1131173A|1982-09-07|Bipolar electrode and method for the productionthereof
    US4460450A|1984-07-17|Coated valve metal anode for the electrolytic extraction of metals or metal oxides
    SU1069633A3|1984-01-23|Anode for producing metals by electroplating
    CA1060842A|1979-08-21|Electrolytic cell
    FI61525B|1982-04-30|ELEKTROLYSCELL
    US3994798A|1976-11-30|Module electrode assembly for electrolytic cells
    US4391695A|1983-07-05|Coated metal anode or the electrolytic recovery of metals
    CA1053607A|1979-05-01|Electrolytic cell including cathode busbar structure cathode fingers, and anode base
    PL95784B1|1977-11-30|ELECTROLYZER SYSTEM WITH VERTICAL ELECTRODES
    US3803016A|1974-04-09|Electrolytic cell having adjustable anode sections
    CA1220761A|1987-04-21|Double l-shaped electrode for brine electrolysis cell
    FI82488C|1991-03-11|ELEKTRODKONSTRUKTION FOER GASBILDANDE MONOPOLAERA ELEKTROLYSOERER.
    US4661232A|1987-04-28|Electrode for electrolytic extraction of metals or metal oxides
    FI67882C|1985-06-10|ELEKTROD FOER ELEKTROLYSCELLER
    US3853738A|1974-12-10|Dimensionally stable anode construction
    US3796648A|1974-03-12|Electrolytic cell having self-aligning anodes
    US3945909A|1976-03-23|Bipolar electrodes and electrolytic cell therewith
    US3455811A|1969-07-15|Electrode system for use in the electrolytic production of manganese dioxide
    US20070205110A1|2007-09-06|Electric Circuit Of An Electrolyzer With Bipolar Electrodes And Electrolysis Installation With Bipolar Electrodes
    US3838035A|1974-09-24|Mercury cell with coated anode
    EP0082643B1|1987-11-04|An electrode structure for electrolyser cells
    同族专利:
    公开号 | 公开日
    JPS56127786A|1981-10-06|
    CA1187838A|1985-05-28|
    DE3005795A1|1981-08-20|
    BE887491A|1981-06-01|
    FR2476150A1|1981-08-21|
    DE3005795C2|1984-12-06|
    ZA81622B|1982-03-31|
    FR2476150B1|1985-09-27|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE478511C|1928-03-07|1929-06-27|Siemens & Halske Akt Ges|Method and device for obtaining deposition products with the same physical properties in electrochemical processes|
    IT978581B|1973-01-29|1974-09-20|Oronzio De Nora Impianti|METALLIC ANODES WITH REDUCED ANODIC SURFACE FOR ELECTROLYSIS PROCESSES USING LOW DENSITY OF CATHODIC CURRENT|
    DE2313683C3|1973-03-20|1982-05-06|Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln|Electrolytic cell|
    US4022679A|1973-05-10|1977-05-10|C. Conradty|Coated titanium anode for amalgam heavy duty cells|
    US4013525A|1973-09-24|1977-03-22|Imperial Chemical Industries Limited|Electrolytic cells|DE3406823C2|1984-02-24|1985-12-19|Conradty GmbH & Co Metallelektroden KG, 8505 Röthenbach|Coated valve metal anode for the electrolytic extraction of metals or metal oxides|
    DE3406777C2|1984-02-24|1985-12-19|Conradty GmbH & Co Metallelektroden KG, 8505 Röthenbach|Coated valve metal anode for the electrolytic extraction of metals or metal oxides|
    JP2007312941A|2006-05-24|2007-12-06|Heiwa Corp|Prize-winning part of pachinko game machine|
    US8900439B2|2010-12-23|2014-12-02|Ge-Hitachi Nuclear Energy Americas Llc|Modular cathode assemblies and methods of using the same for electrochemical reduction|
    US8956524B2|2010-12-23|2015-02-17|Ge-Hitachi Nuclear Energy Americas Llc|Modular anode assemblies and methods of using the same for electrochemical reduction|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE3005795A|DE3005795C2|1980-02-15|1980-02-15|Coated metal anode for the electrolytic extraction of metals|
    [返回顶部]